What is the difference between Actual, Standard and Normal Flows?
- Detailed Explanation of Flows and Conditions – Actual, Standard, and Normal Flows:
- Why Use Standardized Flows Instead of Volumetric Flow?
- STP vs NTP
- Normal Cubic Meter (Nm³/h) vs Actual Cubic Meter (Am³/h)
- What are the standard temperature and pressure applications?
- Standard Temperature and Pressure Applications
- Gas Properties and their Dependence on Temperature and Pressure
- STP and NTP Flow
- Gas Mass and Flow
- Volumetric and Mass Flow
- Normal Volume and Standard Conditions
- Molar Volume Examples
- Converting to Standard Conditions
- Standards for Reference Conditions in Gas Measurement
- Example Reference Conditions Across Entities:
Detailed Explanation of Flows and Conditions – Actual, Standard, and Normal Flows:
Actual Flow:
- The volume of gas passing through a system at any given time under the actual operating conditions (i.e., the current temperature, pressure, and density at that point).
- Actual flow can vary significantly depending on these factors, and the units of measurement for actual flow are often actual cubic meters per hour (am³/h) or actual liters per minute (al/min).
- The challenge with actual flow measurements is that they cannot be easily compared between systems or over time unless the temperature and pressure are also considered.
Example:
- If you measure the flow of natural gas at a pressure of 50 bar and a temperature of 35°C, this is an actual flow.
- If the pressure or temperature changes, the actual flow value will change as well.
Standard Flow:
- Standard flow refers to a volumetric measurement of gas flow normalized to a defined set of reference conditions, commonly referred to as standard temperature and pressure (STP) or normal temperature and pressure (NTP).
- The purpose of standardizing the flow measurement is to eliminate variations caused by fluctuations in temperature and pressure, so that measurements can be compared between different systems, locations, and time periods, even if those systems operate under different conditions.
Example
- A gas flow rate of 1000 m³/h at STP means the flow would be adjusted to 0°C and 101.325 kPa, no matter what the actual temperature and pressure are in the field.
- Standardized flow is important in gas custody transfer (for billing purposes) and in situations where precise measurements are required for comparison or regulatory purposes.
Normal Flow
- This term is often used interchangeably with “standard flow,” but it can refer to a set of reference conditions specific to certain industries.
- Normal conditions typically involve 20°C and 101.325 kPa (1 atmosphere of pressure).
- Normalized flow measurements, like Normal Cubic Meters per Hour (Nm³/h), allow for a consistent measurement of gas regardless of where or when it is measured, provided it is adjusted to the same reference conditions.
Example
A flow measurement of 100 Nm³/h means that the gas flow rate is expressed under normal conditions (20°C and 101.325 kPa), even if the actual flow is occurring at a different temperature and pressure.
Refer the below link for the pressure and flow unit conversion calcualtors
Why Use Standardized Flows Instead of Volumetric Flow?
- Gas behavior is highly influenced by temperature and pressure, meaning that the same volume of gas at different pressures and temperatures could contain different amounts of mass. If gas flow were measured using volumetric flow alone, it would be impossible to compare flow rates from different systems or locations without adjusting for those varying conditions.
- Standardized flows are used to ensure that measurements can be made on a consistent basis, regardless of changes in temperature or pressure.
This consistency is critical for:
Inter-system Comparisons
- For instance, in the natural gas industry, standardized flow measurements allow companies to compare their pipeline flow rates to the standard, ensuring consistency across measurements and regions.
Energy Calculations
- Energy content in natural gas or other gases is often based on standardized conditions, allowing energy calculations to be made without the influence of fluctuating environmental conditions.
STP vs NTP
STP (Standard Temperature and Pressure):
Definition:
- STP refers to a fixed set of conditions under which gas volumes are standardized. Different organizations have different standards for STP. The IUPAC (International Union of Pure and Applied Chemistry) standard for STP defines:
- Temperature: 0°C (273.15 K)
- Pressure: 100 kPa (1 bar or 1 atm)
- The NIST (National Institute of Standards and Technology) version of STP uses 101.325 kPa (1 atm), with the same temperature of 0°C. This is the most commonly used definition in the United States.
Applications:
- STP is used primarily for laboratory and scientific applications where conditions must be controlled to measure properties like gas density, molar volume, and other thermodynamic parameters. It also plays a role in defining the ideal gas laws.
NTP (Normal Temperature and Pressure):
Definition:
- NTP is typically defined as:
- Temperature: 20°C (293.15 K)
- Pressure: 101.325 kPa (1 atm)
- NTP is often considered more representative of typical atmospheric conditions. This makes it more relevant for industrial applications, such as gas flow measurement in pipelines, where the temperature and pressure are closer to the actual operating conditions.
Applications:
- NTP is used extensively in industries such as gas distribution and HVAC systems, where processes occur at ambient or slightly elevated temperatures and pressures.
Normal Cubic Meter (Nm³/h) vs Actual Cubic Meter (Am³/h)
Normal Cubic Meter (Nm³/h):
- This measurement refers to the volume of gas at normal conditions (typically 20°C and 101.325 kPa), and is often used to express flow rates in industrial applications or when comparing gas flows from different sources.
- Nm³/h provides a standardized method to compare gas flows despite environmental changes.
Example:
- For example, if gas is flowing at 1000 Nm³/h, this is a normalized measurement, meaning that the flow rate has been adjusted to normal temperature and pressure conditions.
Actual Cubic Meter (Am³/h):
- This is the volume of gas measured under actual flow conditions at a given point in time, where the temperature and pressure are not standardized but correspond to the real-time operating conditions of the system.
Example:
- If you measure the gas flow in a pipeline, and the temperature is 30°C (303 K) and the pressure is 5 bar, the gas flow may be 1000 Am³/h.
- This is the actual flow rate as it exists in the system, and if the temperature or pressure changes, the volume will change as well.
What are the standard temperature and pressure applications?
Standard Temperature and Pressure (STP) or Normal Temperature and Pressure (NTP) are reference conditions used to measure and compare the volume of gases. These conditions are necessary because the volume of a given amount of gas changes depending on the temperature and pressure. By using standard values, we can accurately calculate and compare gas volumes across different systems.
- The volume of a gas changes when its temperature or pressure changes. To avoid confusion, we use standard conditions to define the volume of gas.
- Using standard conditions helps provide a consistent basis for measuring and comparing gas quantities.
Standard Temperature and Pressure Applications
- In industries like oil, gas, and utilities, custody transfer refers to the point at which one company transfers ownership of gas to another. In such cases, gas flow is often measured at standardized conditions (STP or NTP) to ensure accurate and fair measurement of the gas delivered.
- STP/NTP is used to measure and report the volume of gases like natural gas, air, or other industrial gases. This ensures that the measurements are comparable, even if they are taken in different places or times.
- In industries like oil and gas, accurate flow measurement is needed for billing or operational efficiency. By normalizing gas flow to standard conditions, companies can ensure fairness and consistency.
- The energy content of gases is often determined using STP or NTP, as this allows for consistent calculations of energy regardless of varying environmental conditions.
- In scientific experiments, gases are often tested under STP to ensure that results are reproducible and not affected by changing environmental factors.
- Engineers use standard conditions to design systems like pipelines, compressors, and flow meters to handle gases under typical environmental conditions, ensuring safety and efficiency.
Gas Properties and their Dependence on Temperature and Pressure
Gases, by definition, are substances in a gaseous state under defined pressure and temperature. For example, the nitrogen we breathe is a gas. Steam and vapors, although technically gases, are liquids in certain conditions. Thermodynamically, there’s no real distinction between a vapor and a gas.
A key difference between liquids and gases is compressibility gases are compressible, meaning their volume can decrease under pressure, while liquids are generally considered incompressible.
Another important gas property is that its volume increases with temperature. This principle is the basis of how hot air balloons work.
STP and NTP Flow
The relationship between the properties of gases is described by the Ideal Gas Law:
PV=nRT
Where:
- P= gas pressure (Pa or psia)
- n = number of moles (mol or lb-mol)
- V = gas molar volume (m³/mol or ft³/lb-mol)
- T = absolute temperature (K or °R)
- R = universal gas constant (8.314472 m³·Pa·mol⁻¹·K⁻¹ in SI or 10.7316 ft³·psia·lb-mol⁻¹·°R⁻¹ in US customary units)
In simple terms, the volume of a gas is affected by pressure and temperature. If temperature and pressure are known, we can calculate the volume of gas, and vice versa.
Gas Mass and Flow
- Since the mass of a gas stays constant, its volume and density change with pressure and temperature (according to the law of conservation of mass).
- Instead of measuring the gas volume directly, we often measure mass, as it is more stable.
- While gases are often measured using standardized molar volumes (like Scf or Nm³), it’s important to remember that these terms refer to mass, not volume.
- Corrected volume refers to mass divided by density at standard conditions, not actual volume.
Volumetric and Mass Flow
- Volumetric flow (e.g., CFM or m³) refers to gas measured at actual pressure and temperature, and will change with these conditions.
- However, mass flow stays consistent across different pressures and temperatures, making it easier to compare and calculate.
For example, air density at standard conditions is 0.0752 lb/ft³. Using this value, you can calculate mass flow as:
Mass flow rate=Density×Volumetric flow rate
- In systems like vacuum pumps, compressors, and heat exchangers, air pressure and temperature fluctuate, so volumetric flow changes.
- To avoid confusion, systems are often described using mass or standard volume flow, which doesn’t change with pressure or temperature.
Normal Volume and Standard Conditions
- Normal Volume refers to the mass of a gas at standard conditions (like 1 atm and 0°C or 20°C). For example, a normal cubic meter (Ndm³) refers to the mass of 1 liter of gas at these standard conditions.
- To convert between standard and actual conditions, the molar gas volume is needed.
- The Ideal Gas Law allows us to calculate this, and the relationship shows that gas volume is directly proportional to temperature and inversely proportional to pressure.
Molar Volume Examples
Molar volumes at standard conditions:
- At 0°C and 101.325 kPa: Vm = 22.414 m³/kmol
- At 0°C and 100 kPa: Vm = 22.711 m³/kmol
In US customary units:
- At 32°F and 14.696 psia: Vm = 359.0441 ft³/lb-mol
- At 32°F and 14.73 psia: Vm = 358.2154 ft³/lb-mol
Converting to Standard Conditions
The reason for converting to standard conditions is to make flow rates under different conditions comparable.
Standard conditions allow you to express volume in terms of mass or moles, making it easier to calculate and compare across different systems.
Thus, STP and NTP are essentially a way of converting volumetric quantities into mass or molar terms, making them easier to compare under varying conditions.
There is not a single universally accepted standard for temperature and pressure, which is why different organizations might define slightly different reference conditions.
Standards for Reference Conditions in Gas Measurement
Gas compressibility implies that a cubic meter of gas contains varying mass depending on pressure and temperature conditions.
For instance:
- A cubic meter (m³) of air at 100 bar (absolute) and 40 °C has a mass of 112 kg.
- A cubic meter (m³) of air at 1.013 bar (absolute) and 0 °C has a mass of 1.3 kg.
Using mass (e.g., kg/h) clearly defines the flow rate as it doesn’t vary with changing conditions. However, volume-based measurements, such as m³/h, require specifying the reference conditions, as the volume varies with changes in temperature and pressure.
There are two approaches to specifying gas flow:
- Actual Flow Conditions: The volume per unit time is stated at the actual pressure and temperature, which can vary, making direct comparisons challenging.
- Reference Flow Conditions: Expressing flow at defined conditions (e.g., 1 absolute atmosphere at 0 °C, often referred to as “Normal” conditions) allows easier comparison across different conditions. A common notation is “Nm³/h” (normal cubic meters per hour).
Example Reference Conditions Across Entities:
Entity | Temp (°C) | Temp (°F) | Temp (K) | Pressure (kPa) | Pressure (psi) | Molar Volume (m³) | Molar Volume (dm³) |
STP (IUPAC, since 1982) | 0 | 32 | 273 | 100.000 | 145.038 | 0.02270 | 22.699 |
NIST, ISO 10780 (STP) | 0 | 32 | 273 | 101.325 | 146.959 | 0.02240 | 22.402 |
Normal Temp and Pressure (NTP) | 20 | 68 | 293 | 101.325 | 146.959 | 0.02404 | 24.043 |
SATP (IUPAC) | 25 | 77 | 298 | 100.000 | 145.038 | 0.02478 | 24.777 |
EPA | 25 | 77 | 298 | 101.325 | 146.959 | 0.02445 | 24.453 |
CAGI | 20 | 68 | 293 | 100.000 | 145.038 | 0.02436 | 24.361 |
ISO 5011 | 20 | 68 | 293 | 101.3 | 14.69 | 0.02405 | 24.049 |
SPE, OSHA | 16 | 60 | 289 | 101.3 | 14.696 | 0.02371 | 23.714 |
EGIA, OPEC, EIA | 16 | 60 | 289 | 101.6 | 14.73 | 0.02365 | 23.650 |
ICAOs ISA | 15 | 59 | 288 | 101.325 | 146.959 | 0.02363 | 23.633 |
These reference conditions, defined by various agencies, help make flow rates comparable across different conditions. Below are some of the entities and their acronyms:
- IUPAC: International Union of Pure and Applied Chemistry
- NIST: National Institute of Standards and Technology
- CAGI: Compressed Air and Gas Institute
- SPE: Society of Petroleum Engineers
- OSHA: U.S. Occupational Safety and Health Administration
- OPEC: Organization of Petroleum Exporting Countries
- EIA: U.S. Energy Information Administration
- AMCA: Air Movement and Control Association
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